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: Facing an impossible long-range shot, Usopp awakens his Observation Haki for the first time. This allows him to see the "auras" of Luffy, Law, and Sugar through walls from the King's Plateau, enabling him to aim with supernatural precision.
: With the final obstacle cleared, Luffy and Law finally come face-to-face with Donquixote Doflamingo and Trebol at the top of the palace to begin the final showdown. Summary Table One Piece (Dub) Episode 697
: Sugar is moments away from touching Luffy and Law to turn them into toys, which would erase everyone's memories of them. Usopp's perfectly timed shot reaches her just in time. : Facing an impossible long-range shot, Usopp awakens